20) Brad Pitt and Angelina Jolie

Pitt and Jolie met on the set of Mr. & Mrs. Smith in 2004 and continued to top all the media highlights as one of Hollywood's most romantic couples. Now married since 2014, the super couple has six children, and their connection remains a public obsession despite their widely publicized divorce in 2016.
Lately, Pitt is seemingly busy running his own production company, Plan B Entertainment, while Jolie continues her activism and acting career. Their romance, though tumultuous, forms a vital part of Hollywood history.
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Edited by Zainab Shaikh