1) Darth Vader - Star Wars (1977)
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No villain can match the popularity of Darth Vader from Star Wars Franchise. He was a hero before he became this dark vindictive person. He is ruthless and uses brutal methods to achieve what he seeks. He betrayed the Jedi Order and is adamant about turning his son - Luke Skywalker into a dark being like him.
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Edited by Debanjana
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